Cage effect and inverse temperature depe
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Elisey S. Rudakov; Vladimir L. Lobachev; Larisa K. Volkova
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Article
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2011
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John Wiley and Sons
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English
⚖ 171 KB
👁 2 views
## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system