The Visible and Near Ultraviolet Rotation–Vibration Spectrum of HOD

✍ Scribed by A. Jenouvrier; M.F. Mérienne; M. Carleer; R. Colin; A.-C. Vandaele; P.F. Bernath; Oleg L. Polyansky; Jonathan Tennyson

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 95 KB
• Volume: 209
• Category: Article
• ISSN: 0022-2852
• DOI: 10.1006/jmsp.2001.8418

✦ Synopsis

Fourier transform spectrum has been recorded of a H 2 O/D 2 O vapor mixture in the wavenumber range 16,300 to 22,800 cm -1 using a long path cell. 410 lines of HDO are assigned to the OH stretching overtone bands 5ν 3 , 6ν 3 and 7ν 3 plus combination bands. Assignments for the 6ν 3 and 7ν 3 bands represent the first data for the 006 and 007 states and give band origins of 19,836.88 cm -1 and 22,625.50 cm -1 , respectively. Rotational term values for these states are also obtained.