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The vibrational spectrum of the dimethyl ether-water complex

✍ Scribed by A.J. Barnes; T.R. Beech


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
256 KB
Volume
94
Category
Article
ISSN
0009-2614

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✦ Synopsis


Infrared spectra of the dimethyl ether-water comples trapped in argon matrices show an upwards shift of the CH srrctching irrquencies. Comparison is made with the behaviour of other dimethyl ether complexes.


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The infrared spectra, in the 4ooO-200 cm-' region, of water and ammonia co-deposited in nitrogen and argon matrices have been recorded. The spectra have been interpreted in terms of a linearly hydrogenbonded 1: 1 molecular complex, consistent with the results of gas phase molecular beam electric res