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The vibrational spectra of Mn16O3F and its 18O isotopomers: Matrix isolation, isotope shifts, band contour and normal coordinate studies

✍ Scribed by E.L. Varetti; R.R. Filgueira; A. Müller


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
321 KB
Volume
37
Category
Article
ISSN
1386-1425

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✦ Synopsis


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-The mamx rsolatlon spectrum of the very reactive permanganyl fluonde (Mn1603F, Mn'Wo2*'OF, Mn1601S0,F and Mn"O,F) was measured The Conohs coupling constant for the degenerate Mn-0 stretching mode v.,(E) was determined by computer slmulatlon of the 1 r band contour, measured at low temperatures The obtamed data were used for the calculation of an improved force field for MnO,F INlXODUCllON