The vibration-rotation problem in triatomic molecules allowing for two large-amplitude stretching vibrations
โ Scribed by J.C.D Brand; Ch.V.S Ramachandra Rao
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 667 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-2852
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๐ SIMILAR VOLUMES
The present paper reports the derivation of a new theoretical model describing the rotation and vibration of a triatomic molecule. The new method is based on the MORBID (Morse Oscillatory Rigid Bender Internal Dynamics) method (P. Jensen, J. Mol. Spectross: 128, 478-501 (1988): P. Jensen. J. (hcm. S
Motivated by attempts to understand the mechanism(s) by which internal rotation of methyl tops strongly enhances intramolecular vibrational energy redistribution, a vibration-torsion-rotation Hamiltonian has been constructed for molecules containing one C 3ยฃ rotor. Internal rotation is taken to be s