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The versatile coordination chemistry of tricyanoethenolate, [(NC)2C=C(CN)O]−

✍ Scribed by Erik J. Brandon; Glenn P.A. Yap; Arnold L. Rheingold; Atta Arif; Joel S. Miller

Book ID
103109428
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
300 KB
Volume
240
Category
Article
ISSN
0020-1693

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Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space