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The vapour phase complex HFFeF3. An ab inition molecular orbital study

✍ Scribed by G. Scholz

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
378 KB
Volume
206
Category
Article
ISSN
0009-2614

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✦ Synopsis

Similar to the HF-AlF, complex, the HF-FeF3 complex was found to have a C, structure. The HF and FeF3 subunits are nearly undistorted and connected via a long Fe-F bond ( IZ 208 pm, MP2 level). The HF subunit has a nearly free rotation about the FeF3 subunit.

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