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The Vapor Phase Rearrangement of Pinacols

✍ Scribed by Emerson, William S.

Book ID: 126201566
Publisher: American Chemical Society
Year: 1947
Tongue: English
Weight: 151 KB
Volume: 69
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01197a503

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## Abstract Deprotonated phenyl ethylene glycols, on collisional activation, lose water by a negative ion pinacol rearrangement involving phenyl migration. For example, deprotonated benzpinacol undergoes the following reactions: Ph~2~C(OH)C(O^−^)Ph~2~ → [PhCOCPh~3~ – H]^−^ + H~2~O. It is proposed t