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The Vacuum Ultraviolet Absorption Bands of the Pink Afterglow Spectrum of Molecular Nitrogen Revisited at High Resolution

✍ Scribed by Jean-Yves Roncin; Françoise Launay; Harald Bredohl; Iwan Dubois


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
309 KB
Volume
194
Category
Article
ISSN
0022-2852

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✦ Synopsis


The absorption spectrum of the pink afterglow of molecular nitrogen in the vacuum ultraviolet has been analyzed at high resolution. The spectrum exhibits hot bands involving vibrational levels of the electronic ground state as high as v Љ ϭ 19. Experimentally determined term values are derived for v Љ ϭ 0 -19, of which v Љ ϭ 16 -19 were before now poorly known.


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The n 2 band of 35 ClNO 2 at 12.6 mm has been studied by high-resolution Fourier transform spectroscopy. Assignments have been made for 1423 a-type rotational transitions. The band center is found to be 792.7613 cm 01 , and rotational and centrifugal distortion constants have been determined. Measur