The kin&a OC a hydrogen stift reaction was investigated. The proce~ is governed by large tunnel contributions and takes place during the rcarrangcmcnt of a light-gcncratcd. transient hexahydrocarbazole into a srable hcxahydr~bazole. Luge Isotope effects were observed when the migz~tirg hydrogen was
✦ LIBER ✦
The utilization of tunnel effects for mechanistic studies of hydrogen transfer reactions
✍ Scribed by Ulrike Baron; Gunter Bartelt; Alexander Eychmüller; Karlheinz Grellmann; Ulrich Schmitt; Erich Tauer; Horst Weller
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 621 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0047-2670
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