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The use of van der waals molecules to identify spectroscopic origins

✍ Scribed by Joseph A. Blazy; Donald H. Levy

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 366 KB
Volume: 51
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80429-6

No coin nor oath required. For personal study only.

✦ Synopsis

A technique for identifying the origin band of an electronic transition is described. The technique utilizes the increased linewidth of helium van der Waats complexes caused by vibrationa predissociation when the molecular part of the complex is vibrationally excited. The method is applied to the visibic spectrum of chromyl chloride, and we conclude that the ds band of chromyl chloride is not a second electronic origin.

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