𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The use of triple quadrupoles for sequential mass spectrometry: 1—The instrument parameters

✍ Scribed by P. H. Dawson; J. B. French; J. A. Buckley; D. J. Douglas; D. Simmons


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
726 KB
Volume
17
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Triple quadrupoles are becoming widely used in sequential mass spectrometry. The observed spectra are very dependent upon the choice of instrument parameters such as the gas target density, the mode of operation of the central quadrupole, and the direct current levels of the quadrupoles (rod‐offsets) which determine the collision energy and the maximum mass resolutions in each analysing quadrupole. The influence of each of the instrument parameters is discussed with examples of experimental measurements of performance, and the optimum choice of modes of operation is determined.


📜 SIMILAR VOLUMES


The use of triple quadrupoles for sequen
✍ P. H. Dawson; J. B. French; J. A. Buckley; D. J. Douglas; D. Simmons 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 797 KB

## Abstract A detailed exploration of the application of triple quadrupoles in sequential mass spectrometry has been carried out using dimethylmorpholinophosphoramidate as a case study of an ion of relatively high mass and complex structure. Both metastable ion decomposition and dissociation by low

Quadrupole time-of-flight versus triple-
✍ Hanno Steen; Bernhard Küster; Matthias Mann 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

An API 3000 triple-quadrupole instrument and a QSTAR Pulsar quadrupole time-of-flight (TOF) mass spectrometer were compared for the determination of phosphopeptides by precursor ion scanning in both the positive and negative nanoelectrospray ionization modes. The limits of detection for synthetic ph

The fragmentation of the ions of nonan-4
✍ R. A. Yost; C. G. Enke 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 629 KB

## Abstract The fragmentation pathways for the ions generated by electron impact from nonan‐4‐one have been studied using low energy collision induced dissociation in a triple quadrupole mass spectrometer. Over 400 fragmentation pathways have been identified. These results are compared with data fr

Characterization of the disulfides of bi
✍ Federico Maria Rubino; Cinzia Verduci; Rosario Giampiccolo; Salvatore Pulvirenti 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Glutathione and other intracellular low molecular mass thiols act both as the major endogenous antioxidant and redox buffer system and, as recently highlighted, as an important regulator of cellular homeostasis. Such cellular functions are mediated by protein thiolation, a newly recogni