## Abstract A detailed exploration of the application of triple quadrupoles in sequential mass spectrometry has been carried out using dimethylmorpholinophosphoramidate as a case study of an ion of relatively high mass and complex structure. Both metastable ion decomposition and dissociation by low
The use of triple quadrupoles for sequential mass spectrometry: 1—The instrument parameters
✍ Scribed by P. H. Dawson; J. B. French; J. A. Buckley; D. J. Douglas; D. Simmons
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 726 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Triple quadrupoles are becoming widely used in sequential mass spectrometry. The observed spectra are very dependent upon the choice of instrument parameters such as the gas target density, the mode of operation of the central quadrupole, and the direct current levels of the quadrupoles (rod‐offsets) which determine the collision energy and the maximum mass resolutions in each analysing quadrupole. The influence of each of the instrument parameters is discussed with examples of experimental measurements of performance, and the optimum choice of modes of operation is determined.
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