The use of mathematical logic in establishing the structure of complex molecules from their vibrational spectra
✍ Scribed by M. E. Élyashberg; L. A. Moskovkina; L. A. Gribov
- Publisher
- Springer US
- Year
- 1971
- Tongue
- English
- Weight
- 610 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0021-9037
No coin nor oath required. For personal study only.
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The vibrational structure in the X-ray spectra of the molecules CO and BF is calculated. The calalation shows that ffie interference between the vibrational levels of an intermediate electronic state may distort signiicantly the "normal" form cf X-ray emission spectra.
The i.r. and RR spectra of twenty Fe(TPP)LL' type complexes have been measured to locate structure-sensitive bands. In i.r. spectra, band I (135&1330cm-i) and band III (469432cm-') are spinstate sensitive whereas band II (806790cm-') is oxidation-state sensitive and slightly spin-state sensitive in