✦ LIBER ✦
The use of labelled analogues for the determination of mass spectrometric fragmentation mechanisms of cannabinoids. A re-investigation of the formation of the most abundant fragment ion [C15,H19,O2]+ in Δ1(6)tetrahydrocannabinol
✍ Scribed by Edward G. Boeren; Wigger Heerma; Johan K. Terlouw
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 257 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
The routes leading to the formation of the most prominent fragment ion [C~15~H~19~O~2~]^+^ (m/e 231) in the cannabinoid Δ^1(6)^ tetrahydrocannabinol were investigated with the aid of deuterium labelled compounds. A previously proposed mechanism for the two‐step process could be confirmed, but the mechanism for the one‐step route had to be revised.