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The use of isotopic centrifugal distortion differences towards a better definition of the molecular harmonic potential function

✍ Scribed by J.L. Duncan; H. Merson


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
305 KB
Volume
138
Category
Article
ISSN
0009-2614

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✦ Synopsis


It is demonstrated that the use of heavy isotopic differences in quartic distortion constant data contributes to a significant improvement in the definition of the empirically determined harmonic potential function of a molecule, provided the data are determined with sufficient precision. Formaldehyde is used as a test case.

' Work performed as part of an Honours year research project.