✦ LIBER ✦

The use of free energy relationships to rationalize kinetic data in complex solvent mixtures

✍ Scribed by Pilar López; Francisco Sánchez; Rafael Jiménez; Pilar Pérez-Tejeda; María Luisa Moyá

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 284 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:1<57::aid-kin7>3.0.co;2-l

No coin nor oath required. For personal study only.

✦ Synopsis

T h e electron transfer reaction IINH~)4Co"'(L(-pzCOZ)Fe"(CN)5)~ -IINH,),Co"lp-pzCOI)Fe"'(CN)5 1has been studied in water-cosolvent mixtures at ionic strength of I = 0.5 mol dm-' (NaC104). A multipararneter regression was used to rationalize the kinetic data observed. The rnultipararneter regression coefficients have been compared to those obtained for the same reaction to a different ionic strength ( I = 2.8 mol dm-j) The magnitude of these coefficients changes with the ionic strength An explanation i s given for this behavior. 0