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The use of electron-acceptor reagents for the non-destructive detection of some aromatic hydrocarbons and related compounds

โœ Scribed by Heacock, R. A. ;Hutzinger, O.


Publisher
Springer-Verlag
Year
1975
Weight
371 KB
Volume
64
Category
Article
ISSN
0344-838X

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Diazafluorenone (DFO) reacts with a-amino acids and their esters via imine formation to give decarboxylated azomethine ylides and ester substituted azomethine ylides respectively. In the presence of N-methylmaleimide these azomethine ylides undergo stereospecific cycloaddition via endotransition st