The use of electrogenerated hypobromite for the phase transfer catalysed oxidation of benzyl alcohols
โ Scribed by D. Pletcher; N. Tomov
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 265 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0021-891X
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๐ SIMILAR VOLUMES
Successful synergetic combination of the electron-transfer catalyst, TPPMn, and the phase-transfer catalyst, TOMA, in the oxidation of alcohols or hydrocarbons were reported. We have already reported that ethers or alcohols were very readily (within a few minutes at room temperature) oxidized by a
Permanganate, solubilized in methylene chloride with the aid of a phase transfer agent, oxidizes benzyl alcohol to benzaldehyde and bcnzyl ethers to benzoate esters. Although the rate of oxidation of the ether is about an order of magnitude slower than alcohol oxidation, both respond in an identical