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The use of cryogenic solutions applied to study of molecule of fluorides

✍ Scribed by J. Lambard


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
70 KB
Volume
16
Category
Article
ISSN
0022-1139

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✦ Synopsis


Some advantages are provided by the use of cryogenic solvents in order to study the spectroscopy of volatile fluorinated molecules. For instance, greatly solvent diluted matrix. the lowering of the temperature, by slowing down the rotation, simplifies the spectra, leading to narrow absorption peaks. The transparency (Np, 02, rare gases), enables us to operate in more condition (lo-7 molar ratio) than it would be the case in a solid With such dilutions, the molecule is generally observed as a mono, mer, thus allowing the study of naturally associated forms.


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