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The use of crown ethers to access new M[Al2R6X] species. Synthesis and crystal structure of [K · dibenzo-18-crown-6] [Al2Me6Cl] · 2 C6H6

✍ Scribed by Jerry L. Atwood; Duane C. Hrncir; Robin D. Rogers


Publisher
Springer Netherlands
Year
1983
Tongue
English
Weight
471 KB
Volume
1
Category
Article
ISSN
0923-0750

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## Abstract The potassium salt K(C~5~H~5~BMe) (8) can be obtained from 2‐(Me~3~Sn)C~5~H~5~BMe (7)/KO__t__Bu in toluene in essentially quantitative yield. Metalation of 1‐(dimethylamino)‐3‐methylene‐1,2,3,6‐tetrahydroborinine (9) with MN(SiMe~3~)~2~ (M = Na, K) in toluene afforded the unsolvated sal