The use of coherent spectroscopy in the study of intramolecular tunneling processes in excited triplet states
β Scribed by M.E. Tarrasch; C.R. Chen; C.B. Harris
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 431 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Intramolcculv
tunnchq in the lowc\t tr@ct \tJtc of cyclopcntanonc i\ invcstgntcd using optically dctccted electron spit1 cohcrcncc tcchniyucs. The results, when analyred with cuchange theory, show that the tunneling wxurs on ;1 tlmc sc:k kmgcr than the triplet hfetimc of cyclopcntanone in contrast to what has been reported earlier by Shain and Shdrnoff.
π SIMILAR VOLUMES
## Rcceivcd 21 Jl?ly 1975 We present a theoretical model for describing spin coherence in photoexcited triplet states in zero-field under the influence of vibronic relaxation. From a comparison with experimental results in parabenzoquinone we obtain information about the properties of the excited
A theory of microwave band-to-band transitions in triplet Frenkei excitons in the coherent migration limit for a one-dimensional exciton associated with translationally equivalent molecules is developed. Because of selective spin-orbit coupling to the maw\_ tic sublevels, an anisotropy in the zero f