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The use of CNDO/force and compliance constant methods in evaluating quadratic potential functions of carbonyl and formyl fluorides

✍ Scribed by A. S. N. Murthy; Shoba Ranganathan


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
522 KB
Volume
4
Category
Article
ISSN
0192-8651

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✦ Synopsis


cNDo/Force and compliance constant methods were applied to define general quadratic potential functions for FzCO and HCOF. A satisfactory set of compliants was obtained by suitably scaling down the stretching and stretch-stretch elements of the initial force constant matrix, evaluated by the CNno/force approach, followed by fitting the compliants to available experimental data.