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The use of borane–amine adducts as versatile palladium-catalyzed hydrogen-transfer reagents in methanol

✍ Scribed by Michel Couturier; Brian M Andresen; John L Tucker; Pascal Dubé; Steven J Brenek; Joanna T Negri

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 63 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00300-8

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✦ Synopsis

The scope of borane-amine adducts as reducing agents is broadened through palladium-catalyzed methanolysis capable of reducing a wide variety of functional groups. Hence, borane mediated reduction of a benzamide followed by a tandem methanolysis/hydrogenolysis of the resulting borane-benzylamine adduct allows chemoselective removal of an N-benzoyl in the presence of an O-benzoyl.

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ChemInform Abstract: The Use of Borane—A

ChemInform Abstract: The Use of Borane—Amine Adducts as Versatile Palladium-Catalyzed Hydrogen-Transfer Reagents in Methanol.

✍ Michel Couturier; Brian M. Andresen; John L. Tucker; Pascal Dube; Steven J. Bren 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

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