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The use of acetylenic aldehydes in Baylis–Hillman reactions: synthesis of versatile allyl propargyl alcohols

✍ Scribed by Palakodety Radha Krishna; Empati Raja Sekhar; V. Kannan


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
158 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


The utility of acetylenic aldehydes in Baylis-Hillman reactions giving allyl propargyl alcohols in moderate to good yields is reported.


📜 SIMILAR VOLUMES


The chalcogeno-Baylis-Hillman reaction:
✍ Tadashi Kataoka; Tetsuo Iwama; Shin-ichiro Tsujiyama; Tatsunori Iwamura; Shin-ic 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 841 KB

The chalcogeno-Baylis-Hillman reaction catalyzed by sulfides and selenides, the group 16 element compounds, in the presence of Lewis acids was developed. The reactions proceeded smoothly by the use of 1 equiv of Tic14 to give the coupling products in moderate to good yields. Bischalcogenides and re