The unimolecular chemistry of protonated glycine and the proton affinity of glycine: a computational model
β Scribed by Einar Uggerud
- Book ID
- 105887040
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 496 KB
- Volume
- 97
- Category
- Article
- ISSN
- 1432-2234
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π SIMILAR VOLUMES
The energies of protonation and Na' cationization of glycine (GLY) and its (GLY -H + Na) salt in the gas phase were calculated using ab initio calculations. The proton affinity of GLY, valued at the MP2/6-31G\*//3-21G level, is 937 kJ mol-'. The amino function is confirmed to be the most favourable
## OMS Letters Dear Sir, ## How Does Isotopic Substitution Affect the Gas-phase Proton Affinity of Glycine? A Combined Experimental and Ab Initio Study Recently there has been widespread interest in the fundamental properties and reactivity of gas-phase ions derived from biomolecules. For examp