๐”– Bobbio Scriptorium
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The Unimolar Tosylation1of alpha- and beta-Methyl-d-glucosides

โœ Scribed by Compton, Jack


Book ID
111890704
Publisher
American Chemical Society
Year
1938
Tongue
English
Weight
531 KB
Volume
60
Category
Article
ISSN
0002-7863

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Solvolytic studies of the highly crowded
โœ Kwang-Ting Liu; Mann-Yan Kuo ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 240 KB

In the titled system the remarkably high tosylate/bromide solvolysis rate ratio of 1.56~10~ : 1 indicates a highly strained ground state, and the reverse order of reactivity for substrate having 1-(4-trifluoromethyl)phenyl vs. that having 1-(3-trifluoromethyl)phenyl suggests the twisting of the aryl