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The Unexpected Role of CO in CH Oxidative Addition by a Cationic Rhodium(I) Complex

✍ Scribed by Michael Montag; Leonid Schwartsburd; Revital Cohen; Gregory Leitus; Yehoshoa Ben-David; Jan M. L. Martin; David Milstein


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
126 KB
Volume
46
Category
Article
ISSN
0044-8249

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Effect of CO on the Oxidative Addition o
✍ Michael Montag; Irena Efremenko; Revital Cohen; Linda J. W. Shimon; Gregory Leit 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 782 KB

## Abstract Sequential addition of CO molecules to cationic aryl–hydrido Rh^III^ complexes of phosphine‐based (PCP) pincer ligands was found to lead first to CH reductive elimination and then to CH oxidative addition, thereby demonstrating a dual role of CO. DFT calculations indicate that the oxi