The Unexpected Formation of a Novel Fluorinated Triene

✍ Scribed by Igor Shevchenko; Vasyl Andrushko; Enno Lork; Gerd-Volker Röschenthaler

• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 83 KB
• Volume: 2003
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/ejic.200390007

✦ Synopsis

Abstract

Bis[bis(dialkylamino)phosphanyl]methane (1) and 4,4,4‐trifluoro‐3‐(trifluoromethyl)‐2‐butenenitrile (2) unexpectedly gave triene 3. According to the X‐ray structure analysis compound 3 exists in the solid state exclusively as one isomer. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)