𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond

✍ Scribed by Miguel A. Ciriano; Maurizio Lanfranchi; Luis A. Oro; Jesús J. Pérez-Torrente; Antonio Tiripicchio; Marisa Tiripicchio Camellini


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
276 KB
Volume
469
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Intermolecular Insertion of an N,N-Heter
✍ Guy C. Lloyd-Jones; Roger W. Alder; Gareth J. J. Owen-Smith 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 301 KB

## Abstract The reaction of 2‐[^13^C]‐1‐ethyl‐3‐isopropyl‐3,4,5,6‐tetrahydropyrimidin‐1‐ium hexafluorophosphate ([^13^C~1~]‐1‐PF~6~) with a slight excess (1.03 equiv) of dimeric potassium hexamethyldisilazide (“(K‐HMDS)~2~”) in toluene generates 2‐[^13^C]‐3‐ethyl‐1‐isopropyl‐3,4,5,6‐tetrahydropyrim