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The two-photon excitation spectrum of pyrene

✍ Scribed by P.R. Salvi; P. Foggi; E. Castellucci


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
502 KB
Volume
98
Category
Article
ISSN
0009-2614

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✦ Synopsis


Recri\ed 10 Jnnuarv I983

The t\o-photon excitation spectrum of pgrene md the polarization ratio R have been merrsured up to 52100 A. Eridencc of 3 strong vibronic coupling benreen the first 'Bz,, state and 'Aa states induced by bZu vibwtional modes is presented. By means of n nnd comparison with previously calculated energy values. alJ the g electronic states have been as-&red. thus oburining ;1 fairly good overA scheme of the orderins of the valence-state levels up to 2000 A. An orderofmagnitude estimate of the absolute tao-photon cross section of the strong 28350 cm-t band is given.


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