The triplet state of azobenzene
โ Scribed by Sandra Monti; Enrico Gardini; Pietro Bortolus; Edmond Amouyal
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 505 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The quenchmg rate constants (k4) for trtplet energy transfer from aromattc hydrocarbons to trans and CIS azobenzene have been measured b) flash hmettc spectrophotometry For both Isomers the plot log k, Lersus ET of the donors shows a 'non-classical" behawour A model of the energy-transfer process. uhlch accounts for the experImenta A, values, allows the energy of the 1oHes.t trlplet state of both Isomers to be determIned
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Although it has been unambigously established that the lowest triplet state of benzophenone and many of its derivatives [2,3] is a 3(n, z\*) [l],