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The Triphosphide (tBu3Si)2P3Na: Formation, X-ray and Ab initio Structure Analyses, Protonation and Oxidation to Triphosphane (tBu3Si)2P3H and Hexaphosphanes (tBu3Si)4P6☆

✍ Scribed by Nils Wiberg; Angelika Wörner; Hans-Wolfram Lerner; Konstantin Karaghiosoff; Dieter Fenske; Gerhard Baum; Alk Dransfeld; Paul von Ragué Schleyer

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
885 KB
Volume
1998
Category
Article
ISSN
1434-1948

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## Abstract The sodium pentaphosphide dimer [(__t__Bu~3~Si)~3~P~5~Na~2~(THF)]~2~ has been synthesized in high yield from the reaction of four equivalents of the sodium silanide __t__Bu~3~SiNa with P~4~. X‐ray quality crystals of the sodium pentaphosphide dimer [(__t__Bu~3~Si)~3~P~5~Na~2~(THF)]~2~ (