The Trifluoromethoxycarbonyl Radical CF3OCO
β Scribed by Stefan von Ahsen; Julia Hufen; Helge Willner; Joseph S. Francisco
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 131 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0947-6539
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## Abstract The thermal decomposition of trifluoromethoxycarbonyl peroxy nitrate, CF~3~OC(O)O~2~NO~2~, has been studied between 278 and 306 K at 270 mbar total pressure using He as a diluent gas. The pressure dependence of the reaction was also studied at 292 K between 1.2 and 270 mbar total pressu
Pulsed VUV radlatton forms CT j vta the reacrton CT3Br + /IV (I 21 nm) -cr; + Br The t\vo fluorescence transmons. nczr 250 and 600 nw.are seen to be nUo\\ed transIttons wth time constants of 12 + 3 and 18 f 3 ns. respectively These time constants and also quenching with nitrogen show that the two er
The anisotropic ESR spectra of the CFsX-radical anions (X = Cl, Br, I) have been observed following 7 irradiation at 77 K of solid solutions containing up to 5 mole % of the CF3X parent compound in tetramethylsilane (TMS), neopentane, and 2-methyltetrahydrofuran. The resolution of the line component