The tracer diffusion of dye anions in nylon 6 film
β Scribed by G. Chantrey; I. D. Rattee
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 498 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The tracer diffusion coefficients of three S35-labeled dyes in nylon 6 film have been determined. The diffusion coefficients show marked concentration dependence, but this takes a form different from that shown by chloride ions in a related study. It is not possible to explain the data on the basis of electrostatic factors as in earlier work in which diffusion was accompanied by a freeenergy change. A diffusional interaction between dye molecules is postulated which takes the form of a free-volume saturation effect leading to an upper limiting diffusion coefficient at adsorption levels which depend upon the polymer order and the characteristics of the diffusing ion.
π SIMILAR VOLUMES
The dyeing kinetics of an acid dye (C.I. Acid Blue 40) in a nylon 6 film were investigated using partition-cell and film-roll methods at 80Β°C and pHs 2.3 and 3.05. The concentration dependence of diffusion coefficient of the dye in the nylon substrate measured by both methods was interpreted in term
The sorption behavior of acid dyes by a nylon 6 film was investigated in the presence and absence of a bolaform electrolyte. The time dependence of the sorption changed with the pH values of the dye bath. At pH 3, equilibrium sorption was not established even after the immersion of the film in the a