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The tracer diffusion of dye anions in nylon 6 film

✍ Scribed by G. Chantrey; I. D. Rattee


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
498 KB
Volume
18
Category
Article
ISSN
0021-8995

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✦ Synopsis


The tracer diffusion coefficients of three S35-labeled dyes in nylon 6 film have been determined. The diffusion coefficients show marked concentration dependence, but this takes a form different from that shown by chloride ions in a related study. It is not possible to explain the data on the basis of electrostatic factors as in earlier work in which diffusion was accompanied by a freeenergy change. A diffusional interaction between dye molecules is postulated which takes the form of a free-volume saturation effect leading to an upper limiting diffusion coefficient at adsorption levels which depend upon the polymer order and the characteristics of the diffusing ion.


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