The total synthesis of robustadial A and B dimethyl ethers
โ Scribed by Salomon, Robert G.; Lal, Kasturi.; Mazza, Samuel M.; Zarate, Eugene A.; Youngs, Wiley J.
- Book ID
- 121287466
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 891 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
We recently reported total synthesis of the ethyl eeter dimethyl ether of carnoric acid (I) (l), which is unusual among tricyclic diterpenoida in containing an angular aarboxyl function. We now report a new method for construction of the 11,12-dihydroxylated C-ring in this system. The new approach
Carnosic acid (XII) (1) is unusual among tricarbocyclic diterpenoidr in that its angular substituent is in an oxidation state higher than methyl. We wish to report the substantiation of its structure by total synthesis