𝔖 Bobbio Scriptorium
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The total synthesis of radermachol

✍ Scribed by Qingping Jiang; Balawant S. Joshi; S. William Pelletier


Book ID
104225297
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
218 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis


The red pigment, radermachol(1). has been synthesized from 1,4-dimethoxynaphthelene In thrrfeen steps.

Radermachol (l),' a red prgment Isolated from Radermachera xylocarpa, has a fused aromatlc structure not encountered previously in any other natural product A retrosynthebc analysis (Scheme 1) indicated the preparation of 3 as a key Intermediate for introduction of the dimethylacryloyl group and subsequent cycllzation.


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