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The total synthesis of delphinine: A stereoselective synthesis of an advanced relay compound

✍ Scribed by K. Wiesner; E. W. K. Jay; C. Demerson; T. Kanno; J. Křepinský; Lizzie Poon; T. Y. R. Tsai; A. Vilím; C. S. Wu

Book ID
112695428
Publisher
Springer
Year
1970
Tongue
English
Weight
428 KB
Volume
26
Category
Article
ISSN
1420-682X

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✍ Jiong Chen; John N. Marx 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 182 KB

A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereo,selective vinyl radical eyelization, which gives a 10:1 ratio of 21 to 22.