The torsional spectrum of CH3SiH3
β Scribed by N Moazzen-Ahmadi; I Ozier; H Jagannath
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 947 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The multipleβchannel reactions SiH~3~ + SiH(CH~3~)~3~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD (singleβpoint) method. The rate constants f
## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
## Abstract Disilylmethane is available in a fourβstep synthesis starting with phenylsilane. This is converted into chlorophenylsilane by HCl/AlCl~3~. The reaction of PhSiH~2~Cl and dibromomethane with magnesium in tetrahydrofuran affords bis(phenylsilyl)βmethane, which yields bis(bromosilyl)methan
The far-infrared torsional spectrum of CH 3 SiD 3 has been measured in a continuing effort to quantify the coupling between the small amplitude vibrations and the large amplitude internal rotation of the methyl group in symmetric tops. It is hoped that this will help in understanding the role of tor