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The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry.

✍ Scribed by Uwe Rosenthal; Vladimir V. Burlakov; Perdita Arndt; Wolfgang Baumann; Anke Spannenberg


Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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Structure of an β€œIsodiimine” Complex: Bi
✍ Dr. Michael Veith πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 225 KB πŸ‘ 1 views

The action of methanol on the reddish brown compound does not lead to liberation of trimethylsilyl groups but instead, according to to loss of cyclopentadienyl groups with formation of a brown diamagnetic complex of unknown structure which can be vacuum sublimed at 110Β°C. Its 'H-NMR spectrum contai