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The Thermolysis of Cyclopropyl Azides

✍ Scribed by Dr. Günter Szeimies; Udo Siefken; Rolf Rinck

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
213 KB
Volume
12
Category
Article
ISSN
0044-8249

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## Abstract 1‐(Alkylthio)cyclopropyl azides ‐ readily accessible from the corresponding chlorides and bromides ‐ are smoothly decomposed at 70°C with nitrogen evolution. The main process is a ring enlargement to 2‐(alkylthio)azetines **2**, accompanied by cleavage to thiocyanate and alkene. Reactio

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