The Thermodynamics of Ionization of Anil
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W. van de Poel; P. J. Slootmaekers
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Article
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2010
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Wiley (John Wiley & Sons)
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Thermodynamic parameters of ionization of a number of substituted anilinium ions were measured in water and in ethanol-water mixtures at 25ยฐC. Both the enthalpy and entropy of ionization show extreme values in a solvent mixture containing 0,90 mole fraction of water. Free energy values decrease smoo