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The thermodynamic effect of fluorine as a substituent: Vinylic CF2 and CFH and allylic CF2C

โœ Scribed by William R. Dolbier Jr.; Karl S. Medinger; Arthur Greenberg; Joel F. Liebman

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
423 KB
Volume
38
Category
Article
ISSN
0040-4020

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๐Ÿ“œ SIMILAR VOLUMES

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. IV. Reactions of ยทCF3 + CF3CH2CF2ยท and CF3CH2CF2ยท + CF3CH2CF2ยท
โœ Shane R. Smith; Bert E. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 161 KB ๐Ÿ‘ 2 views

Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. II. Reactions of โ€ขCF3 +CF3CH2CH2โ€ข and CF3CH2CH2โ€ข + CF3CH2CH2โ€ข
โœ Derek R. McDowell; Jennie Weston; Bert E. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 634 KB

Disproportionation/combination rate constant ratios, k , / k , , have been measured for the collision between CF3CH2CH2 and CF3 radicals to be 0.022 ? 0 002 and for CF3CH2CH2 and CF3CH2CH2 radicals to be 0.100 IT 0.002. Comparison to previous work from this laboratory for the reaction of CF3CH2CHCI

A kinetic study of the reaction of fluor
A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ยฑ 2 K
โœ Timothy J. Wallington; Michael D. Hurley; Jichun Shi; M. Matti Maricq; Jens Sehe ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 807 KB

A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.