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The thermochemistry of some polycyclic compounds

✍ Scribed by V.P. Kolesov; S.M. Pimenova; V.A. Lukyanova; T.S. Kuznetsova; M.P. Kozina

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
159 KB
Volume
30
Category
Article
ISSN
0021-9614

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✦ Synopsis

The standard massic energies of combustion of eight polycyclic compounds were measured at T s 298.15 K by static-bomb combustion calorimetry. The standard enthalpies of vaporization and sublimation were measured in a Calvet microcalorimeter, or adiabatic vaporization calorimeter, or derived from ebulliometric measurements of the vapour pressure as a function of temperature. The standard molar enthalpies of formation in the condensed and gaseous states were obtained from these data. The peculiarities in the strain energies of polycyclic compounds are discussed.

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