The Thermally Induced Solid-State Polymerization Reaction in Halogenoacetates
β Scribed by Epple, Matthias ;Kirschnick, Holger
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1996
- Tongue
- English
- Weight
- 824 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2940
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β¦ Synopsis
Halogenoacetates I Solid-state reactions / Polyglycolide / Thermal analysis / Polymerization Nine salts of halogenoacetic acids MOOC-CH2-X were prepared and characterized by their thermochemical reactivity. It was found that in seven cases elimination of MX led to polymerization of the organic part of the molecule. The 0009-2940/96/0909-1123 $15.00+.25/0 * Dedicated to Prof. Giinther Klar on the occasion of his 60th
π SIMILAR VOLUMES
substitution reaction is well known for a pair of solid metal halides and in organic solution chemistry, but-to our Halogenoacetates react with metal halides in the solid state via halogen exchange. This was studied in detail for the reaction knowledge-unknown so far for solid organic compounds. bet