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The Thermally Induced Solid-State Polymerization Reaction in Halogenoacetates

✍ Scribed by Epple, Matthias ;Kirschnick, Holger


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
824 KB
Volume
129
Category
Article
ISSN
0009-2940

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✦ Synopsis


Halogenoacetates I Solid-state reactions / Polyglycolide / Thermal analysis / Polymerization Nine salts of halogenoacetic acids MOOC-CH2-X were prepared and characterized by their thermochemical reactivity. It was found that in seven cases elimination of MX led to polymerization of the organic part of the molecule. The 0009-2940/96/0909-1123 $15.00+.25/0 * Dedicated to Prof. Giinther Klar on the occasion of his 60th


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The Solid-State Substitution Reaction be
✍ Matthias Epple; Roland Seifert πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 229 KB

substitution reaction is well known for a pair of solid metal halides and in organic solution chemistry, but-to our Halogenoacetates react with metal halides in the solid state via halogen exchange. This was studied in detail for the reaction knowledge-unknown so far for solid organic compounds. bet