The thermal unimolecular isomerization of bicyclo[3,1,0]hexane
โ Scribed by Frey, H. M.; Smith, R. C.
- Book ID
- 120030709
- Publisher
- Royal Society of Chemistry
- Year
- 1962
- Weight
- 370 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0014-7672
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๐ SIMILAR VOLUMES
The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =
## Abstract The thermal isomerization of 1,1โdivinylcyclopropane has been investigated in the gas phase in the temperature range of 238 to 288ยฐC and for pressures in the range of 4 to 12 torr. The isomerization to 1โvinylcyclopentene is homogeneous and kinetically first order and almost certainly u
## Abstract The reversible isomerization of __cis__โheptaโ1,3โdiene to __cis__โ2โ__trans__โ4โheptadiene via a 1,5 hydrogen shift has been investigated kinetically at nine temperatures in the range of 475ยฐ to 531ยฐK. Equilibrium is reached near 94% reaction. Some __cis__โ2โ__cis__โ4โheptadiene is als