## Abstract The thermal unimolecular decomposition of bromocyclobutane has been investigated over the temperature range of 791β1224 K using the technique of very lowβpressure pyrolysis (VLPP). HBr elimination is the sole mode of decomposition under the experimental conditions. No evidence could be
The Thermal Unimolecular Decomposition of Chlorocyclobutane
β Scribed by Cocks, A. T.; Frey, H. M.
- Book ID
- 125968376
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 374 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The thermal unimolecular decomposition of propynal was investigated behind reflected shock waves. The decomposition proceeded via the molecular path to produce acetylene and carbon monoxide. The Arrhenius expression for the high pressure rate constants is k, = 10'4.93 exp ( -7 1 kcal mol-'/RT) s-' i
The thermal dccompodlion of formyl fluoride in Ar has been studed behind shock waves over the temperature range i 160-1480 K and the total density fa"ge (7.18-18.6) x IO\* mol cmm3. The decomposition was monitored by means of IR em&ion from the CH stretching of the reactant and the fundamental band