4‐Methyl‐1,2,5‐hexatriene (13) has been prepared and subjected to gas‐phase pyrolysis. Above 220°C, 13 rearranges reversibly to both __trans__‐5‐hepten‐1‐yne (14) and its __cis__‐isomer 15. Formation of 14 is faster than that of 15. These isomerisations are accompanied by a slower irreversible rearr
✦ LIBER ✦
The Thermal Intramolecula Rearrangement of 7-Methyl-1,3,5-cycloheptatriene in the Gas Phase. I. The Kinetics of the Unimolecular Positional Isomerization via a 1,5 Hydrogen Transfer
✍ Scribed by Egger, Kurt W.
- Book ID
- 126946960
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 721 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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## Abstract In the gas phase, __cis__,__trans__‐1,5‐cyclooctadiene (\documentclass{article}\pagestyle{empty}\begin{document}$ {\mathop 1\limits\_\sim} $\end{document}) undergoes a unimolecular rearrangement to __cis__,__cis__‐1,5‐cyclooctadiene (\documentclass{article}\pagestyle{empty}\begin{docume