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The thermal decomposition of α-diazoacetophenone

✍ Scribed by Peter Yates; T.J. Clark

Publisher
Elsevier Science
Year
1961
Tongue
French
Weight
230 KB
Volume
2
Category
Article
ISSN
0040-4039

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✦ Synopsis

ALTHCUGH the uncatalyzed, thermal decomposition of several a-substituted a-diazoketones has yielded ketenes, these have not been isolated from the decomposition products of a-diazoketones of type RCCXXN2 and investigation of such products has been scant. 3 In connection with a study of the Wolff 4 rearrangement we have examined the thermal decomposition of a-diazoacetophenone in dodecane. Tine reaction was carried out in the dark at L!+O" under nitrogen -for 12 hr. The major product (2&), m.p. 288-289' dec., AKBZ 5.68~, was

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✍ Peter Yates; Donald G. Farnum 📂 Article 📅 1960 🏛 Elsevier Science 🌐 French ⚖ 213 KB

h IUCEXT reoort from this Laboratory1 has described an investigation of the reaction of a-diazoacetophenone with sodium methoxide in dilute solution. We now report on the reactions of a-diazoacetophenone with sodium methoxide in concentrated sclution and with potassium t-butoxide, which have additi