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The thermal decomposition of uranyl formate and the preparation of ammonium uranyl formate, (NH4)2UO2(COOH)4

✍ Scribed by E.R. Russell; M.L. Hyder


Publisher
Elsevier Science
Year
1976
Weight
149 KB
Volume
12
Category
Article
ISSN
0020-1650

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Treatment of UO 3 with pure triflic acid TfOH at 110 Β°C or with boiling triflic anhydride TfOTf afforded [UO 2 (OTf) 2 ] (1) in high yields. The latter was also prepared by the reaction of UO 3 with TfOH in water, or by dehydration of [UO 2 (OTf) 2 (H 2 O) n ] in boiling TfOTf. Anhydrous [Ce(OTf) 4