The thermal decomposition of polyvinylchloride—iii.: An investigation of discolouration
✍ Scribed by W.C. Geddes
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 981 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0014-3057
No coin nor oath required. For personal study only.
✦ Synopsis
Absorption spectra of thermally degraded PVC films are recorded for a number of polymer samples submitted to various dehydrochlorination conditions and in the presence of stabilizers. Correlations are drawn between colour in degraded PVC and dehydrochlorination; the spectra are also discussed qualitatively with special reference to stabilization. The average polyene sequence length in degraded PVC is calculated using an ozonization technique and compared with values derived from peroxide data and from absorption spectra.
📜 SIMILAR VOLUMES
The presence of dicumyl peroxide, benzoyl peroxide, cumene hydroperoxide or azobisisobutyronitrile in PVC leads to increased dehydrochlorination at 150 ° in nitrogen. Hydroperoxide groups introduced during ozonization of degraded PVC have similar effects on the thermal stability of PVC but attempts
The products of thermal decomposition of 1,3,5trinitrohe~.d~dro 1,3,5trkzine (RDS) in vacuum hae been determined mass spectrometriczdly belo\\ and above the melting point. Employins a cell with an elongated orifice to form d collimated beam, RDS decomposition products acre identified M ithin 3 fea m
Analysis of drop size distributions in lean liquid-liquid dispersions. A.1.Ch.E. J. 26, 991-1000. Narsimhan, G., Nejfelt, G. and Ramkrishna, D., 1984, Breakage functions for droplets in agitated liquid-liquid dispersions.